Halar ® / ECTFE Coatings

Performance Polymers and Coatings offers wide applications of  Halar® /ECTFE  coatings to a broad range of chemical processing, medical, scientific and industrial parts.

Halar® coatings, made from ECTFE (Ethylene Chlorotrifluoroethylene), are high-performance Fluoropolymer coatings known for their exceptional chemical resistance, durability, and electrical insulation properties. They are widely used in industries requiring protection against corrosive environments and extreme conditions.

Halar® ECTFE is a melt processable fluoropolymer manufactured by Solvay. The material’s chemical structure (a 1:1 alternating copolymer of ethylene and chlorotrifluoroethylene) makes it useful in a wide variety of applications, especially as a coating or lining.

Halar® ECTFE coatings offer excellent chemical resistance, good electrical properties, a broad-use temperature range from cryogenic to 300°F (150°C).

HALAR® coating is extremely resistant to high and low temperatures, is impact resistant, and also resists chemicals, corrosion and electricity. Usually used to coat products that may be exposed to high amounts of friction, because a HALAR® coating will minimize the amount of wear that the products suffer.

Halar® ECTFE Coatings have been used successfully by coating applicators  since 1992 for fire safety and corrosion protection of exhaust duct systems that must meet the FM4922 fire safety standard. Halar®  coated ductwork offers exceptional surface smoothness reducing or eliminating build up and corrosion.

Halar® coatings have also been used to replace PVDF sheet linings in ultrapure water (UPW) systems. It is a tough material with good impact strength.These characteristics have made Halar® the material of choice for many applications across multiple industries. It has been widely utilized in the chemical, pharmaceutical, and microelectronics industries for chemical resistance

Key Properties of Halar ® / ECTFE Coatings:

  • Chemical Resistance – Excellent resistance to strong acids, bases, and organic solvents. Halar®  exhibits excellent barrier properties; 10 to 100 times better than those of PTFE or FEP to oxygen, carbon dioxide, chlorine gas or hydrochloric acid. Halar® resists a wide variety of corrosive chemicals and organic solvents, including strong acids, chlorine and aqueous caustics.
  • High Temperature Tolerance – Capable of performing under extreme temperatures, Halar®  coatings are suitable for applications ranging from cryogenic to high heat settings. Can withstand temperatures up to 150°C (302°F).
  • Electrical Insulation – (Low dielectric constant, making it ideal for electrical components.) The dielectric constant of Halar®  coatings is low and stable across a broad temperature and frequency range. The dielectric strength is 2000V/mil (80 kV/mm) in 1 mil thickness
  • Low Permeability – Acts as a strong barrier against moisture, gases, and corrosive chemicals.
  • Mechanical Strength – High impact resistance and wear resistance. With its high impact strength and resistance to corrosion, Halar®  ensures that coated products can withstand physical stress and environmental factors, prolonging their lifespan.
  • Non-Stick & Low Friction – Reduces material build-up and enhances performance in fluid handling systems.
  • Flammability Halar®  meets UL 94 V-O flame test in thicknesses as low as 7 mils (0.175 mm). When placed in a flame, unlike most thermoplastics, Halar® coatings do not melt or drip. Char is formed, which serves as an oxygen and heat transfer barrier. On removal of flame, it immediately extinguishes. Halar®  coatings will not ignite or propagate flame in atmospheres which contain up to 52% of oxygen. In addition, Halar® has excellent low smoke properties.
  • Thermal..Properties
    Halar®  ECTFE fluoropolymer is UL certified for use in non-load bearing applications requiring continuous service at temperatures to 300°F (150°C). 
  • Purity
    Static soak testing in Ultra-Pure Water (UPW) and High Purity Chemicals show extremely low levels of metallic and organic extractables. Additional dynamic rinse data also validates Halar® as a material suitable for high purity systems in the semiconductor, biotech, and pharmaceutical industries.

Industrial Applications of Halar® /ECTFE Coatings:

  1. Chemical Processing – Used in tanks, pipes, valves, and pumps for corrosion protection.
  2. Semiconductor Industry – Protects components from harsh chemicals during manufacturing.
  3. Pharmaceutical & Food Processing – Ensures compliance with hygiene standards and prevents contamination.
  4. Aerospace & Automotive – Used in fuel systems, electrical insulation, and lightweight protective coatings.
  5. Power & Electronics – Coats wires, cables, and circuit boards for insulation and corrosion resistance.

Halar®  coatings are a preferred choice for industries requiring long-term performance in harsh environments. Their ability to resist chemicals, heat, and wear makes them an invaluable solution for critical applications.

Halar Coatings Markets and Applications

High Purity Applications
Static soak testing conducted on Halar in ultrapure water and high purity chemicals shows extremely low levels of metallic and organic extractables. Additional dynamic rinse data validates Halar coatings as suitable for high purity systems in the semiconductor, biotech, and pharmaceutical industries. Halar exhibits very low fluoride ion leach out.

Exhaust Duct Coatings
Halar coated stainless steel exhaust duct systems are designed to handle a wide range of corrosive exhaust streams found in a variety of industrial applications, including clean rooms. Halar provides the following benefits to exhaust ducting:

  • Excellent chemical resistance
  • Excellent corrosion resistance
  • Outperforms plastic and FRP duct with improved safety and corrosion resistance
  • Reduction or elimination of the buildup of salt deposits and debris that can reduce airflow. Approved by Factory Mutual for use in fume and smoke exhaust systems without sprinklers.

Pulp & Paper Industry
Halar ECTFE has a history of success as a protective coating in aggressive environments due to the fact that it is not sensitive to pH, moisture, or strong oxidizers and it is not attacked by a broad variety of chemicals. Halar powder coatings deliver seamless and smooth corrosion protection.

Semiconductor
Halar ECTFE coatings meet stringent standards for purity, chemical resistance, and thermal stability demanded on semiconductor processing equipment and in clean rooms. It is widely used in the semiconductor industry on vessels, process equipment, racking/fixturing devices, and exhaust duct systems. Halar purity, surface smoothness, chemical resistance, & fire resistance are key characteristics for the semiconductor market.

Fluid Handling Systems
Delivery, storage, filtration and processing are some of the steps integral to a fluid handling system. Halar ECTFE is widely used by industrial coating applicators on components used in the fluid handling industry because of its superior ability to withstand extreme chemicals and temperatures. Halar coatings are the best choice for key components such as: valves, pipe, tanks, vessels, and heat exchangers.

Waste Disposal
Waste products from many industries are likely to be corrosive, ignitable, reactive and/or toxic. Halar ECTFE offers superior performance and resistance to acids used in etching, stripping and cleaning processes, as well as abrasion resistance to slurries and effluents. Storage containers, piping and fittings, agitators, valves and other components coated with Halar provide reliable performance for waste disposal systems.

ECTFE/Halar Statistics
Tensile Strength (ASTM D1708) 6,600 psi
Thickness
0.004″ – 0.006″ per coat
Use Temperature
300°F max
Adhesion (ASTM D4541)
1,933 psi
Salt Spray Resistance (ASTM B117)
4,000 hrs
Hardness (ASTM D3363)
> 8 H
Chemical Resistance (ASTM D543)
Excellent
ECTFE/Halar Statistics
Tensile Strength (ASTM D1708) 6,600 psi
Thickness
0.004″ – 0.006″ per coat
Use Temperature
300°F max
Adhesion (ASTM D4541)
1,933 psi
Salt Spray Resistance (ASTM B117)
4,000 hrs
Hardness (ASTM D3363)
> 8 H
Chemical Resistance (ASTM D543)
Excellent

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